Efficient one-pot three component reaction of aniline derivatives with cyanoamide and triethyl orthoformate at reflux in toluene affords N0-aryl-N-cyanoformamidines in high yields just by the distillation of the azeotrope toluene/ethyl alcohol. Labelled d9-Amitraz is prepared by the application of this procedure in the synthesis of formamidine pesticides family.
Titolo: | Development of one-pot three component reaction for the synthesis of N’-aryl-N cyanoformamidines, essential precursors of formamidine pesticides family |
Autori: | |
Data di pubblicazione: | 2016 |
Rivista: | |
Handle: | http://hdl.handle.net/20.500.12317/5846 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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